cnr_iadc_6700_85d3_922b eng UTF8 dataset service Axiom Docker Install Axiom Docker Install 555-555-5555 123 Irrelevant St. Nowhere AK 99504 USA nobody@example.com pointOfContact 2026-05-29 ISO 19115-2 Geographic Information - Metadata Part 2 Extensions for Imagery and Gridded Data ISO 19115-2:2009(E) 3 column row temporal H-NMR functional groups & tracers conc., GVB, Ny-Alesund, May2019-Jun2020 2026-05-29 creation erddap.s4polarin.eu/erddap-cnr cnr_iadc_6700_85d3_922b Marco Paglione Italian National Research Council - Institute of Atmospheric Sciences and Climate m.paglione@isac.cnr.it https://metadata.iadc.cnr.it/geonetwork/srv/api/records/0e110925-1f3d-4013-b048-e5a47ca3be6f information web browser Background Information Background information from the source information originator Marco Paglione m.paglione@isac.cnr.it contributor H-NMR functional groups & tracers conc. - GVB, Ny-Alesund - May2019-Jun2020. PM1 organic aerosol functional groups distribution as measured by H-NMR, expressed both in ?molH m-3 and ?gC m-3 (using conversion factors described in Decesari et al., 2007) & mass concentrations of some molecular tracers (namely Methane-sulphonate (MSA), Hydroxy methane-sulfonate (HMSA) Di- and Tri- methyl amines (DMA and TMA)), levoglucosan, expressed in ?g m-3 Marco Paglione Italian National Research Council - Institute of Atmospheric Sciences and Climate m.paglione@isac.cnr.it https://metadata.iadc.cnr.it/geonetwork/srv/api/records/0e110925-1f3d-4013-b048-e5a47ca3be6f information web browser Background Information Background information from the source information pointOfContact aerosol alcoxy alesund aliphatic alkyls amine amines anomeric anomeric-vynil ar-h aromatic atmosphere atmospheric carbon climate conc. concentration content council data di-methyl dimethyl-amine dma dry functional groups gruvebadet gvb h-c h-c-c h-c-o h-nmr h-nmr functional groups hmsa hydrogen hydroxy hydroxy-methane hydroxyl hydroxyl/alcoxy hydroxymethane-sulphonate identifier institute italian jun2020 levoglucosan ma trimethyl-amine mass matter may2019 may2019-jun2020 methane methane-sulphonate methyl methyl-amine methyl-amines mono mono- msa national nmr ny-alesund o-ch-o optical optical properties organic organic aerosol organic molecular tracers particles particulate pm1 position properties research sciences station substituted sulphonate sum tma tracers tri tri- tri-methyl unfunctionalized unsaturated unsaturated/substituted vynil wsoc theme Italian National Research Council - Institute of Atmospheric Sciences and Climate project time mass_concentration_of_aromatic_functional_groups_in_organic_aerosol mass_concentration_of_anomeric-vynil_functional_groups_in_organic_aerosol mass_concentration_of_h-c-o_functional_groups_in_organic_aerosol mass_concentration_of_h-c-c=_functional_groups_in_organic_aerosol mass_concentration_of_methane-sulphonate_hydrogen_in_organic_aerosol mass_concentration_of_methyl-amines_hydrogen_in_organic_aerosol mass_concentration_of_h-c_functional_groups_in_organic_aerosol mass_concentration_of_aromatic_functional_groups_in_organic_aerosol mass_concentration_of_h-c-o_functional_groups_in_organic_aerosol mass_concentration_of_h-c-c=_functional_groups_in_organic_aerosol mass_concentration_of_methane-sulphonate_carbon_in_organic_aerosol mass_concentration_of_methyl-amines_carbon_in_organic_aerosol mass_concentration_of_h-c_functional_groups_in_organic_aerosol atmosphere_mass_content_of_particulate_organic_matter_dry_aerosol_particles mass_concentration_of_methane-sulphonate_in_organic_aerosol mass_concentration_of_levoglucosan_in_organic_aerosol mass_concentration_of_hmsa_in_organic_aerosol mass_concentration_of_tma_in_organic_aerosol mass_concentration_of_dma_in_organic_aerosol gruvebadet latitude longitude theme CF Standard Name Table v70 CC BY-NC: This license allows reusers to distribute, remix, adapt, and build upon the material in any medium or format for noncommercial purposes only, and only so long as attribution is given to the creator. Italian National Research Council - Institute of Atmospheric Sciences and Climate largerWorkCitation project Unidata Common Data Model TimeSeries largerWorkCitation project eng geoscientificInformation 1 11.8942 11.8942 78.9177 78.9177 seconds 2019-05-24T00:00:00Z 2020-06-01T00:00:00Z H-NMR functional groups & tracers conc., GVB, Ny-Alesund, May2019-Jun2020 2026-05-29 creation Marco Paglione Italian National Research Council - Institute of Atmospheric Sciences and Climate m.paglione@isac.cnr.it https://metadata.iadc.cnr.it/geonetwork/srv/api/records/0e110925-1f3d-4013-b048-e5a47ca3be6f information web browser Background Information Background information from the source information originator Marco Paglione m.paglione@isac.cnr.it contributor H-NMR functional groups & tracers conc. - GVB, Ny-Alesund - May2019-Jun2020. PM1 organic aerosol functional groups distribution as measured by H-NMR, expressed both in ?molH m-3 and ?gC m-3 (using conversion factors described in Decesari et al., 2007) & mass concentrations of some molecular tracers (namely Methane-sulphonate (MSA), Hydroxy methane-sulfonate (HMSA) Di- and Tri- methyl amines (DMA and TMA)), levoglucosan, expressed in ?g m-3 ERDDAP tabledap 1 11.8942 11.8942 78.9177 78.9177 seconds 2019-05-24T00:00:00Z 2020-06-01T00:00:00Z tight ERDDAPtabledapDatasetQueryAndAccess https://erddap.s4polarin.eu/erddap-cnr/erddap/tabledap/cnr_iadc_6700_85d3_922b ERDDAP:tabledap ERDDAP-tabledap ERDDAP's tabledap service (a flavor of OPeNDAP) for tabular (sequence) data. Add different extensions (e.g., .html, .graph, .das, .dds) to the base URL for different purposes. download H-NMR functional groups & tracers conc., GVB, Ny-Alesund, May2019-Jun2020 2026-05-29 creation Marco Paglione Italian National Research Council - Institute of Atmospheric Sciences and Climate m.paglione@isac.cnr.it https://metadata.iadc.cnr.it/geonetwork/srv/api/records/0e110925-1f3d-4013-b048-e5a47ca3be6f information web browser Background Information Background information from the source information originator Marco Paglione m.paglione@isac.cnr.it contributor H-NMR functional groups & tracers conc. - GVB, Ny-Alesund - May2019-Jun2020. PM1 organic aerosol functional groups distribution as measured by H-NMR, expressed both in ?molH m-3 and ?gC m-3 (using conversion factors described in Decesari et al., 2007) & mass concentrations of some molecular tracers (namely Methane-sulphonate (MSA), Hydroxy methane-sulfonate (HMSA) Di- and Tri- methyl amines (DMA and TMA)), levoglucosan, expressed in ?g m-3 OPeNDAP 1 11.8942 11.8942 78.9177 78.9177 seconds 2019-05-24T00:00:00Z 2020-06-01T00:00:00Z tight OPeNDAPDatasetQueryAndAccess https://erddap.s4polarin.eu/erddap-cnr/erddap/tabledap/cnr_iadc_6700_85d3_922b OPeNDAP:OPeNDAP OPeNDAP An OPeNDAP service for tabular (sequence) data. Add different extensions (e.g., .html, .das, .dds) to the base URL for different purposes. download H-NMR functional groups & tracers conc., GVB, Ny-Alesund, May2019-Jun2020 2026-05-29 creation Marco Paglione Italian National Research Council - Institute of Atmospheric Sciences and Climate m.paglione@isac.cnr.it https://metadata.iadc.cnr.it/geonetwork/srv/api/records/0e110925-1f3d-4013-b048-e5a47ca3be6f information web browser Background Information Background information from the source information originator Marco Paglione m.paglione@isac.cnr.it contributor H-NMR functional groups & tracers conc. - GVB, Ny-Alesund - May2019-Jun2020. PM1 organic aerosol functional groups distribution as measured by H-NMR, expressed both in ?molH m-3 and ?gC m-3 (using conversion factors described in Decesari et al., 2007) & mass concentrations of some molecular tracers (namely Methane-sulphonate (MSA), Hydroxy methane-sulfonate (HMSA) Di- and Tri- methyl amines (DMA and TMA)), levoglucosan, expressed in ?g m-3 ERDDAP Subset 1 11.8942 11.8942 78.9177 78.9177 seconds 2019-05-24T00:00:00Z 2020-06-01T00:00:00Z tight ERDDAP_Subset https://erddap.s4polarin.eu/erddap-cnr/erddap/tabledap/cnr_iadc_6700_85d3_922b.subset search Subset Web page to facilitate selecting subsets of the dataset download physicalMeasurement time double Time Arom_H float aromatic groups (Ar-H) mass concentration in aerosol WSOC by H-NMR Anom_vynil_H float anomeric-vynil groups (O-CH-O) mass concentration in aerosol WSOC by H-NMR Sug_Alc_Eth_Est_H float aliphatic hydroxyl/alcoxy groups (H-C-O) mass concentration in aerosol WSOC by H-NMR Polysub_aliph_Chains_H float unsaturated/substituted groups (H-C-C=) mass concentration in aerosol WSOC by H-NMR MSA_H float Methane-sulphonate hydrogen concentration Amines_H float Sum of methyl-amines (mono-, di and tri- methyl amines) hydrogen concentration Aliph_Chains_H float unfunctionalized alkyls (H-C) groups mass concentration in aerosol WSOC by H-NMR Arom_C float aromatic groups (Ar-H) mass concentration in aerosol WSOC by H-NMR Anom_vynil_C float anomeric-vynil groups (O-CH-O) mass concentration in aerosol WSOC by H-NMR Sug_Alc_Eth_Est_C float aliphatic hydroxyl/alcoxy groups (H-C-O) mass concentration in aerosol WSOC by H-NMR Polysub_aliph_Chains_C float unsaturated/substituted groups (H-C-C=) mass concentration in aerosol WSOC by H-NMR MSA_C float Methane-sulphonate carbon concentration Amines_C float Sum of methyl-amines (mono-, di and tri- methyl amines) carbon concentration Aliph_Chains_C float unfunctionalized alkyls (H-C) groups mass concentration in aerosol WSOC by H-NMR WSOC_NMR_C float WSOC NMR C MSA_mass float Methane-sulphonate mass concentration in PM1 Levoglucosan_mass float Levoglucosan Mass concentration in PM1 HMSA_mass float Hydroxy-methane sulphonate (HMSA) Mass concentration in PM1 TMA_mass float Tri-methyl amine (TMA) Mass concentration in PM1 DMA_mass float Di-methyl amine (DMA) Mass concentration in PM1 station_id String Gruvebadet Axiom Docker Install Axiom Docker Install 555-555-5555 123 Irrelevant St. Nowhere AK 99504 USA nobody@example.com distributor OPeNDAP DAP/2.0 https://erddap.s4polarin.eu/erddap-cnr/erddap/tabledap/cnr_iadc_6700_85d3_922b.html order Data Subset Form ERDDAP's version of the OPeNDAP .html web page for this dataset. Specify a subset of the dataset and download the data via OPeNDAP or in many different file types. download https://erddap.s4polarin.eu/erddap-cnr/erddap/tabledap/cnr_iadc_6700_85d3_922b.graph order Make-A-Graph Form ERDDAP's Make-A-Graph .html web page for this dataset. Create an image with a map or graph of a subset of the data. mapDigital dataset 2019-05-24T00:00:00Z to 2020-06-01T00:00:00Z Ambient aerosol particles with Dp<1 ?m (PM1) were sampled by a High-Volume Sampler (TECORA eco-highvol equipped with digital PM1 sampling inlet, nominal flow 500 lpm) on pre-washed and pre-baked quartz-fiber filters (PALL, Ø= 18cm). Sampling time: 3-4 days per sample for collecting sufficient aerosol loading for the detailed chemical analyses on the filters. 2020-09-30T00:00:00Z After sampling the filters were stored in a freezer and then shipped in thermal insulated boxes to the CNR-ISAC laboratory in Bologna, Italy, where they were kept frozen at about -20º C until extraction and chemical analyses. About half of each filter was used for the off-line characterization by TOC-analyzer, Ion-chromatography and H-NMR (as described in the paper) performed in Bologna. 2021-01-01T00:00:00Z Aliquots of the aerosol extracts were dried under vacuum and re-dissolved in deuterium oxide (D2O) for organic functional group characterization by H-NMR spectroscopy), as described in the present paper and in previous works (i.e., Paglione et al., 2024). The H-NMR spectra were acquired at 600 MHz in a 5 mm tube using a Varian Unity INOVA spectrometer, at the NMR facility of the Department of Industrial Chemistry of the Bologna University. 2022-01-01T00:00:00Z On the basis of the range of frequency shifts, the signals are attributed to H-C containing specific functionalities (Decesari et al., 2000, 2007). Organic hydrogen concentrations directly measured by H-NMR were converted to organic carbon using stoichiometric H/C ratios specifically assigned to functional groups using the same rationale described in previous works (Paglione et al., 2024). The sum of NMR functional group concentrations expressed in C constitutes the total WSOC measured by H-NMR. 2022-01-01T00:00:00Z Some organic tracers were identified in the H-NMR spectra on the basis of their characteristic patterns of resonances and chemical shifts, using for this scope libraries of reference spectra from the literature (of standard single compounds and/or mixtures from laboratory/chamber experiments and/or from ambient field studies at near-source stations). Among such tracers, methane-sulfonic acid (MSA) and low-molecular-weight alkyl amines (namely, di- and tri- methyl amines, DMA and TMA respectively) were quantified, as well as levoglucosan and hydroxy-methane sulfonate (HMSA) 2026-05-29T14:42:32Z (local files) 2026-05-29T14:42:32Z https://data.iadc.cnr.it/erddap/tabledap/hnmr_functional_groups__tracers_conc__gvb_nyalesund__may2019jun2020_7bdtje.das This record was created from dataset metadata by ERDDAP Version 2.24